Product ID:CAIKLEEN 41 SPRAY, (DG41S-16)
MSDS Date:11/01/1994
FSC:6850
NIIN:00N067019
MSDS Number: CBWLG

CAIG LABORATORIES INC

16744 W. BERNARDO DR
SAN DIEGO, CA 92127-1904
US

Emergency Phone: 800-441-3637;800-424-9300(CHEMTREC)

Info Phone: 619-451-1799

Preparer: MARK K LOHKEMPER

Cage: 55403

CAIG LABORATORIES INC

POWAY, CA 92064 US

Telephone: 858-486-8388

Cage: 55403

ETHANE,1,1-DICHLORO-1-FLUORO-;

CAS: 1717-00-6

RTECS: KI0997000

Fraction By Weight: 70-75%

OSHA PEL N/K

ACGIH TLV: N/K

4.1, EVAP

RTECS: 9999999ZZ

1,1,1,2-TETRAFLUOROETHANE; (TETRAFLUOROETHANE)

CAS: 811-97-2

Fraction By Weight: 20-30%

OSHA PEL N/K

ACGIH TLV: N/K

ISOPROPYL ALCOHOL (SARA 313)

CAS: 67-63-0

RTECS: NT8050000

Fraction By Weight: 2-5%

OSHA PEL 400 PPM

ACGIH TLV: 400 PPM/500STEL

RATS (SPRAQUE-DAWLEY) 4 HR LC50 62,000 PPM.

RTECS: 9999999ZZ

NON-TOX. >5 GM/KG BODY. CARDIAC

RTECS: 9999999ZZ

& FETAL TOX 20,000 PPM. NOEL 8,000 PPM. REPRO

RTECS: 9999999ZZ

AMES ASSAY NOT ACTIVE.

RTECS: 9999999ZZ

ACTIVE UP TO 13 MG/L. HUMAN LYMPHOCYTE, NOT ACTIVE,

RTECS: 9999999ZZ

MOUSE MICRONUCLEUS, NOT ACTIVE, UP TO 96,000 PPM. FOR

RTECS: 9999999ZZ

DO NOT INDUCE VOMIT, CONT

RTECS: 9999999ZZ

DRINK. DO NOT GIVE STIMULANTS OR ADRENALIN

RTECS: 9999999ZZ

AFTER USE.

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL:RESP IRRIT. VAP IS HVR/AIR & CAN
CAUSE SUFFOCATION BY REDUCING OXYG AVAIL FOR BRTHG. BRTHG HIGH CONC
OF VAP MAY CAUSE LT-HEAD, DIZZ, SHORTNESS OF BRTH, & MAY LEAD TO
NARCOSIS, CARDIAC IRREGS, UN CON/DEATH. EYE:VAP & LIQ CAN IRRIT.
SKIN:PRLNGD/RPTD CONT CAN CAUSE MOD IRRIT, DEFAT, DERM. LIQ CONT
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS:CAN CAUSE FROSTBITE.
INGEST:DISCOMFORT DUE TO VOLAT OF SOLV WOULD BE EXPECTED. SIMILAR
SYMPS AS FOR INHAL.
Medical Cond Aggravated by Exposure:WITH HIGH EXPOSURE LEVELS, EFFECTS
CAN INCLUDE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION
(INTOXIFICATION) AND CARDIAC ARRHYTHMIA.

First Aid:INHAL:REMOVE TO FRESH AIR. GIVE OXYG IF INDICATED BY
QUALIFIED OPERATOR. DO NOT GIVE STIMULANTS/ADRENALIN (EPINEPHRINE).
CALL MD. EYE:MOVE AWAY FROM EXPOS INTO FRESH AIR. FOR DIRECT CONT,
HOLD LIDS AP ART & FLUSH AFFECTED EYE(S) W/CLEAN WATER FOR @ LST 15
MIN. IF IRRIT PERSISTS, CALL MD. SKIN:CLEANSE AFFECTED AREA(S)
W/MILD SOAP & WATER. APPLY MEDICATED SKIN CREAM. IF IRRIT PERSISTS
SEEK (ING 11)

Flash Point Method:TCC
Flash Point:NONE
Lower Limits:7.3%
Upper Limits:16.1%
Extinguishing Media:DRY CHEM, CARBON DIOXIDE, HALON, POLAR/ALCOHOL
FOAM/WATER SPRAY IS REC. WATER MAY BE INEFTIVE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. MOVE UNDMGED CNTNRS FROM FIRE AREA IF IT CAN BE DONE W/OUT RISK.
USE WATER SPRAY TO KEEP CNTNRS COOL.
Unusual Fire/Explosion Hazard:INTENSIVE HEAT CREATED BY FIRE WILL CAUSE
AEROSOLS TO BURST.

Spill Release Procedures:EVACUATE AREA & AVOID BRTHG VAPS. SPILLED MATL
MAY BE ABSORBED INTO ANY ABSORB MATL. WEAR APPROP PROT EQUIP
INCLUDING NIOSH/MSHA APPROVED RESPIRATORY PROTECTION AS CONDITIONS
WARRANT. VENTILATE AREA T IL ODOR IS GONE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT EXPOSE ANY AEROSOL CAN TO
SUNLIGHT OR TEMPERATURES ABOVE 120F TO PVNT POSS BURSTING. ALL
AEROSOL CAUTIONS APPLY- USE IN WELL VENTILATED AREAS.
Other Precautions:USE & STORE IN COOL, DRY WELL VENT AREAS AWAY FROM
HEAT, HOT SURFS & ALL SOURCES OF IGNIT. PROT CNTNRS FROM PHYSICAL
DMG. INDOOR STOR SHOULD MEET OSHA STDS & APPROP CODES. AS W/ANY
CHEM PREPARATION-US E ONLY AS DIRECTED & WASH HANDS (ING 13)

Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN . NOT NECESSARY UNLESS USED IN AN
UNVENTILATED AREA OR IN HIGH CONCENTRATIONS (SEE EXPOSURE LIMITS,
FIRE AND EXPLOSION HAZA RD DATA).
Ventilation:KEEP EXPOS BELOW LIMS (FIRE & EXPLO HAZ DATA). KEEP WINDOWS
OPEN. LOC EXHST-WHEN USED REPEATEDLY IN QTY.
Protective Gloves:SOLVENT RESISTANT GLOVES WHEN HNDLG LIQ.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER . NOT NECESSARY WITH ADEQUATE VENTILATION.
Work Hygienic Practices:AVOID BREATHING VAPORS AND CONTACT WITH SKIN OR
EYES, USE ADEQUATE VENTILATION.
Supplemental Safety and Health
MATLS TO AVOID:RXN), SODIUM POTASSIUM, CALCIUM, MAGNESIUM, ZINC, MOLTEN
ALUMINUM, BARIUM & LITHIUM SHAVINGS. STRONG OXIDIZING AGENTS. ALSO,
SOME DESICCANTS MAY REACT WITH 141B. EFTS OF OVEREXP:TOX STU DIES
OF 141B:ACUTE INHAL:ALBINO (ING 5)

Boiling Pt:B.P. Text:SEE ING 1
Vapor Pres:SEE ING 1
Vapor Density:SEE ING 1
Spec Gravity:SEE ING 1
Evaporation Rate & Reference:SEE ING 1
Solubility in Water:0.17 WT% @ 77F
Appearance and Odor:CLEAR, COLORLESS LIQUID. SLIGHT ETHEREAL/SWEET
ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS & ALKALIS, REACTIVE METALS E.G.,POWDERED/FRESHLY ABRADED
ALUMINUM (MAY CAUSE STRONG EXOTHERMIC (SUPP DATA)
Stability Condition to Avoid:AVOID OPEN FLAMES AND HIGH TEMPS. AVOID
ALL POSSIBLE SOURCES OF IGNITION.
Hazardous Decomposition Products:COMBUSTION MAY YIELD HYDROCHLORIC AND
HYDROFLUORIC ACIDS; AND CARBONYL HALIDES SUCH AS PHOSGENE.

Waste Disposal Methods:COMPLY WITH FEDERAL, STATE AND LOCAL LAWS AND
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.